The last 16 matches were decided from the winners and runners-up in each of the groups and were:

• Brazil (Winner Grp A) v Chile (Runner-up Grp B) 28.06.14 - Belo Horizonte - 5pm

• Columbia (Winner Grp C) v Uruguay (Runner-up Grp D) 28.06.14 - Rio de Janeiro - 9pm

• Holland (Winner Grp B) v Mexico (Runner-up Grp A) 29.06.14 - Fortaleza - 5pm

• Costa Rica (Winner Grp D) v Greece (Runner-up Grp C) 29.06.14 - Recife - 9pm

• France (Winner Grp E) v Nigeria (Runner-up Grp F) 30.06.14 - Brasilia - 5pm

• Germany (Winner Grp G) v Algeria (Runner-up Grp H) 30.06.14 - Porte Alegre - 9pm

• Argentina (Winner Grp F) v Switzerland (Runner-up Grp E) 01.07.14 - Sao Paulo - 5pm

• Belgium (Winner Grp H) v USA (Runner-up Grp G) 01.07.14 - Salvador - 9pm